So Will Chemistry Teachers Have to Order New Posters Now?

Move over Copernicium! A collaboration of scientists from the Lawrence Livermore National Laboratory in California (one of our customers - we're so proud!), and the Joint Institute for Nuclear Research in Russia are being recognized today for officially creating two new elements! Scientists first created these elements in 1999 and 2000, respectively, by slamming lighter atoms together to see if they would stick. After a lengthy experimentation and review process by the International Unions of Pure and Applied Chemistry and Physics they are now certified and ready to take their rightful spots as the heaviest members of the periodic table.

Both of these elements are radioactive and exist for less than a second before decaying into lighter atoms. For now the elements are being referred to by their element numbers, 114 and 116, since the discovers are still in the process of submitting their recommendations.

It's probably a good thing that the naming process is limited only to the researchers that actually discovered the elements. Somehow I think if it was left up to an online poll our kids would be learning the atomic weight of "Bieberum."

Read more about the announcement here or here.

FAQ: Chemical Compatibility

We all know oil and water don’t mix. Same goes for acids and bases or this guy and gravity. But what about Kerosene and cellulose acetate? Or Trichloroethylene and silver?

To answer these questions we have our frequently referenced Chemical Compatibility Chart for general laboratory filtration products. Since using the correct filter material is vital to the success of a separation process we are constantly expanding our knowledge base of chemicals used with our filtration products. We currently have data on over 70 chemicals and their recommendation level for filtration materials such as Polycarbonate, Nylon and Teflon.                        

Curious about a chemical that isn’t listed yet? Just ask us about it we’ll be happy to help you out.

Do You Trust Me?

According to a recent survey from Laboratory Equipment magazine on the usage of meters and monitors in lab experiments, most researchers do in fact trust their instrumentation; only 1% indicated that they were dissatisfied with their existing equipment. Another sign of trust: 71% of respondents plan to purchase direct replacements for their existing products when they buy new equipment.

You can take a look at these charts on what sort of meters and monitors are beings used and what they are being used for.

New Hydrogen Gas Sensing Method Uses Commercially Available Membrane Filters

Scientists at Northern Illinois University recently published a new approach for fabricating hydrogen gas sensors by depositing palladium onto commercially available filtration membranes.  This creates networks of ultrasmall palladium nanowires without the traditional obstacles of nanofabrication (tedious production, potential contamination).  Palladium, besides poisoning Iron Man, is highly selective to Hydrogen gas and therefore commonly used in room-temperature solid-state Hydrogen sensors.

The new method involves a network of ultrasmall palladium nanowires (<10nm) being placed on 60 micron thick membranes with a nominal filtration pore diameter of 20nm. The end result is that this new type of fabrication method outperformed traditional hydrogen sensors, such as continuous reference film, by providing higher sensitivity and shorter response times. Better hydrogen sensing can lead to greater efficiency in areas such as steel manufacturing and clean energy research.

Thomas Graham: Father of Colloid Chemistry

Have you ever wondered where you would be without Thomas Graham? If you are a chemist or membrane scientist, you probably should. Scientists of many disciplines are indebted to Thomas Graham for his groundbreaking studies on gas flow through microporous membranes. His work, which included creating Graham’s Laws of Diffusion to describe the relative permeation rate of two gases, was instrumental in the creation of colloidal chemistry and the advancement of membrane science.

In terms of real world applications, Graham’s efforts are a precursor to inventions ranging from the artificial kidney to the atomic bomb. His feats are even more impressive when you consider that in order to perform his experiments he had to first generate the necessary gases himself, and also that his selection of membrane materials was limited to whatever objects he could find, such as rubber balloons, animal bladders, and thin metal sheets.

Thomas Graham was born in Edinburgh, Scotland in 1805 and enrolled in the University of Glasgow at the tender age of 14! He went on to become Professor of Chemistry at Anderson’s College (now part of Strathclyde University) and then at University College London. In 1854, Graham was named Master of the Mint, a position once held by Sir Isaac Newton. Even though this was considered to be more of an honorary title at the time, Graham invested himself so heavily in its duties that he actually suspended his research for several years. The position was permanently retired following his death in 1869.

Thomas Graham’s influence has grown considerably since his passing. In addition to Graham’s Laws for diffusion and effusion of gases, he introduced the terms gel, sol, colloids, crystalloids, and dialyzer into the scientific lexicon. Other important contributions include his determining the formulas of the PxOy polyatomic ions, and in the 1850’s he hypothesized that a membrane machine could be created that would separate the blood toxins that built up in kidney failure, paving the way for modern kidney dialysis. His tenacity was rewarded with several honors in his lifetime, including the Copley Medal of the Royal Society, the Royal Medal of the Royal Society (twice), and the Prix Jecker of the Paris Academy of Sciences.

Sources:
“Thomas Graham,” D. Lane and J. Solon, Woodrow Wilson Leadership Program in Chemistry, The Woodrow Wilson National Fellowship Foundation, CN 5281, Princeton, NJ 08543; http://www.woodrow.org/teachers/ci/1992/Graham.html.

“Membrane Pioneers: Thomas Graham,” S. Alexander Stern and Richard W. Baker. Membrane Quarterly. Volume 25, Number 1, January 2010, pgs. 17-19.

Say it ain't so Periodic Table!

Is nothing sacred? In the news today came word that the period table is changing the atomic weights of 10 elements. Instead of being listed as one static value, the atomic weight for these elements will now be displayed as a a range that will more accurately reflect how the elements actually appear in nature.

The change is being made after decades of study and this is the first time in the history of the periodic table that any atomic weights will be altered. Measuring the variance of atomic weights is being used in real world applications for everything from analyzing food purity, to determining which athletes are using performance enhancing drugs!

The elements being changed are: Boron, carbon, chlorine, hydrogen, lithium, nitrogen, oxygen, silicon, sulfur, and thallium.

I hope this doesn't mean we'll have to memorize the table all over again...

You can read more about the change here or here.

Beta Ratios and Filter Efficency

Here is an article that does a great job of explaining what efficiency ratings mean on a filter and how they are calculated, courtesy of the American Filtration & Separation Society.  This is very useful information for filter users and purchasing agents on the practical effects the filter efficiency will have in a real world setting. 

You can read the whole thing here.

Putting on a Shiny Suit: Polycarbonate Membranes get Sputtered!

Polycarbonate (PCTE) track-etch membranes, created decades ago, are finding some new uses in the development of nanotechnology applications.  They owe this new application to their precise pore geometry and organization.  PCTE membranes were previously utilized in the manufacture of single-walled nanotubes (SWNT) due to the relative ease of depositing metal ions on the inside of their pores, then selectively dissolving the PCTE; leaving behind nanotubes for use as super-conducting wires, micro-diode arrays, or magnetic-data storage devices.  

PCTE membranes are traditionally sputter coated with gold for use in scanning electron microscopy (SEM) imaging because it is easier to capture samples on their smooth membrane surface.  Now scientists are developing new ways to utilize PCTE membranes by sputter-coating metal ions on the membrane.  One new use is to construct a biocompatible glucose sensor¹ that can be implanted inside a diabetic’s body.  The membrane is sputter coated with platinum and the pores filled with an enzyme chemically anchored inside the pore.  When excess glucose enters the pores, an electrochemical reaction is started, traveling down the pore to the thin sputtered metal layer, where the signal is picked up and sent to a microprocessor inside the sensor.  The amount of glucose triggering inside each pore determines the strength of the electrical response.  The size of the entire sensor area might be as small as 0.15cm²!  There’s even work filling PCTE pores with photosensitive materials to turn the membrane into flexible solar cells.   

Sputtered membranes are also finding niches in synthesizing catalysts to help make ethanol from syngas (CO and H₂) as this ethanol can be used as an inexpensive and environmentally friendly fuel and fuel additive².  PCTE sheets can be sputter coated with gold and sandwiched onto a Zn sheet to make the necessary anode and cathode for electrodepositing Mn-Cu-ZnO nanowires/tubes.  These nanotubes can then be successfully used as catalysts in CO hydrogenation reaction to produce alcohols.  With so many industrial nations moving towards ethanol as an alternative to petroleum fuels, the need for synthesizing ethanol from available materials may have a new ally in track-etch membranes.

1: A. Kros, M. Gerritsen, V.S.I. Sprakel, N.A.J.M. Sommerdijk, J. Jansen, R.J.M. Nolte, Silica-based hybrid materials as biocompatible coatings for glucose sensors. Sensors and Actuators B, (2001) 68-75.

2: M.Gupta1, V. Kalpathi and J. J. Spivey, Electrodeposition of Cu-ZnO and Mn-Cu-ZnO Nanowires/tubes for Synthesis of Ethanol [abstract] In: Proceedings of the Electrochemical Society, 214^th Meeting Honolulu, Hawaii. October 12-17, 2008.  Abstract no. 0281

Liquid State of Mind

Had your fill of liquids?  You're probably not alone.  According to a new survey by Laboratory Equipment magazine, over 90% of lab researchers use liquid handling equipment, and about 60% are using their equipment either continuously or several times daily.  As for filtration equipment, 52% of respondents are using it - now we just need to get the other 48% on board!!!    

You can check out the full results over at the Laboratory Equipment site: Liquid Handling Dominates Lab Activities