November in Seattle: Turkey and Bus Crashes

We just got blasted with our first winter storm of the year and it was a mean one for Seattle.  Take a look at the video and you can tell that while there are many things we do well here (computer programming, watching soccer), driving around in the snow clearly isn't one of them.  Even our own metro buses can't quite get the hang of it!

Just a reminder, but Sterlitech will be closed this Thursday and Friday for the Thanksgiving holiday (November 25th and 26th. We will open again on Monday the 29th. We wish you all a safe and happy Thanksgiving!

Beta Ratios and Filter Efficency

Here is an article that does a great job of explaining what efficiency ratings mean on a filter and how they are calculated, courtesy of the American Filtration & Separation Society.  This is very useful information for filter users and purchasing agents on the practical effects the filter efficiency will have in a real world setting. 

You can read the whole thing here.

Putting on a Shiny Suit: Polycarbonate Membranes get Sputtered!

Polycarbonate (PCTE) track-etch membranes, created decades ago, are finding some new uses in the development of nanotechnology applications.  They owe this new application to their precise pore geometry and organization.  PCTE membranes were previously utilized in the manufacture of single-walled nanotubes (SWNT) due to the relative ease of depositing metal ions on the inside of their pores, then selectively dissolving the PCTE; leaving behind nanotubes for use as super-conducting wires, micro-diode arrays, or magnetic-data storage devices.  

PCTE membranes are traditionally sputter coated with gold for use in scanning electron microscopy (SEM) imaging because it is easier to capture samples on their smooth membrane surface.  Now scientists are developing new ways to utilize PCTE membranes by sputter-coating metal ions on the membrane.  One new use is to construct a biocompatible glucose sensor¹ that can be implanted inside a diabetic’s body.  The membrane is sputter coated with platinum and the pores filled with an enzyme chemically anchored inside the pore.  When excess glucose enters the pores, an electrochemical reaction is started, traveling down the pore to the thin sputtered metal layer, where the signal is picked up and sent to a microprocessor inside the sensor.  The amount of glucose triggering inside each pore determines the strength of the electrical response.  The size of the entire sensor area might be as small as 0.15cm²!  There’s even work filling PCTE pores with photosensitive materials to turn the membrane into flexible solar cells.   

Sputtered membranes are also finding niches in synthesizing catalysts to help make ethanol from syngas (CO and H₂) as this ethanol can be used as an inexpensive and environmentally friendly fuel and fuel additive².  PCTE sheets can be sputter coated with gold and sandwiched onto a Zn sheet to make the necessary anode and cathode for electrodepositing Mn-Cu-ZnO nanowires/tubes.  These nanotubes can then be successfully used as catalysts in CO hydrogenation reaction to produce alcohols.  With so many industrial nations moving towards ethanol as an alternative to petroleum fuels, the need for synthesizing ethanol from available materials may have a new ally in track-etch membranes.

1: A. Kros, M. Gerritsen, V.S.I. Sprakel, N.A.J.M. Sommerdijk, J. Jansen, R.J.M. Nolte, Silica-based hybrid materials as biocompatible coatings for glucose sensors. Sensors and Actuators B, (2001) 68-75.

2: M.Gupta1, V. Kalpathi and J. J. Spivey, Electrodeposition of Cu-ZnO and Mn-Cu-ZnO Nanowires/tubes for Synthesis of Ethanol [abstract] In: Proceedings of the Electrochemical Society, 214^th Meeting Honolulu, Hawaii. October 12-17, 2008.  Abstract no. 0281

Silver Nanoparticles to Reduce Membrane Biofouling

Scientists at Michigan State University and the PERMEANT Group describes how they are infusing membranes with nanotechnology in order to improve membrane performance, particularly in the field of water purification.  While the use of nanotechnology to expand membrane permeability, selectivity, and resistance has grown more frequent over the last 20 or so years, the new research by these groups is taking this approach in interesting directions.  For instance, on one project they have demonstrated that by adding silver nanoparticles into the polymer matrix of the membrane that the mixture is effective at reducing intrapore biofouling.  Experimentation also shows that this method could also be used to inhibit the biofilm growth on downstream membrane surfaces.  

Hopefully with every little improvement that these teams make will lead them a step closer to their goal of making the world’s supply of drinking water safer for all of us.  

   

You can read more about this research here.

FAQ: Clarification of Fruit (Apple) Juice

Over the years we have seen an increased use of filtration equipment in juice processing, particularly regarding ultrafiltration (UF) or microfiltration (MF) for the clarification of apple juice.  Since it has been demonstrated that membrane filtration can produce yields of 95%-99% - compared to only 80-94% through conventional processes – it is no wonder that filtration methods are growing in prevalence.  The greater yield combined with the reduced time and labor costs have translated to hundreds of thousands of dollars saved for juice processing plants!

If you are considering juice filtration, here a couple of tips to keep in mind:

• The juice must be clear.  Of the four common types of apple juice produced – natural, crushed, clarified, and clear – only clear juice is suitable for membrane processing.    
• Consider ceramic membranes.  More and more fruit juice installations are installing ceramic membranes.  While these do have  a higher cost than other materials, they do offer a higher flux, much longer life, and better resistance to aggressive processing and cleaning conditions. 
• Know your operation.  Since fruit juices have a very low level of retained solids, the optimum mode of operation is the modified batch operation with a partial recycle of retentate.
• Not just for apples.  Other fruit and vegetables that have benefited from membrane filtration include: apricot, carrot, cherry, cranberry, grape, lemon, lime, orange, peach, passion fruit, and tomato.

References:
Ultrafiltration and Microfiltration Handbook.  Cheryan, Munir.  Technomic Publishing Company, 1998.
Microfiltration and Ultrafiltration: Principles and Applications.  Zemon, Leos & Zydney, Andrew.  Marcel Dekker, 1996.

Water Sterilization & Silver

From this recent article in NanoLetters, the American Chemical Society Journal, comes information about a new form of water sterilization out of Stanford University that takes advantages of the unique bacteria-killing properties of silver (the vampire and werewolf killing properties of silver have yet to be proven).  Basically, the proposed multiscale device would perform high speed electrical sterilization of water using a combination of silver nanowires, carbon nanotubes, and cotton.  The end result is that when operating at 100,000 L/(h m²) this device can inactivate greater than 98% of bacteria with only several seconds of total incubation time.

The author’s of this paper mention two interesting reasons for why silver is used in the device.  The first:        

Taking advantage of silver nanowires’ (AgNWs) and CNTs’ [Carbon Nanotube] unique ability to form complex multiscale coatings on cotton to produce an electrically conducting and high surface area device for the active, high-throughput inactivation of bacteria in water.

The other reason described for using silver in water sterilization:

Silver is chosen since it is a very well-known bactericidal agent, and recently a large amount of interest has been spurred by the discovery that silver nanoparticles work extremely well at killing bacteria and can be attached to various surfaces with chemical techniques.    

The outcome of the silver treatment in the author’s experiment provides further evidence of these properties:

The results clearly show that filters not treated with silver, including CNT-only cotton, showed a robust growth of bacteria, while the bacteria concentration in the solutions incubated with AgNW-treated material was reduced to the detection limit of the absorbance system used, at least a 2 to 3 order of magnitude reduction.

All in all, the findings in this paper are encouraging that implementation of this approach can kill microorganisms which cause biofouling in downstream filters.  The authors of the paper state, “Such technology could dramatically lower the cost of a wide array of filtration technologies for water as well as food, air, and pharmaceuticals, where the need to frequently replace filters is a large cost and difficult challenge.”

Their next step is to expand their experimentation to other microorganisms beyond the E. coli that was used for this study.  In their conclusion the authors note that, “Silver is known to be an extremely general agent so it can be expected that this device will also work over a wide array of organisms.” 

We’ll continue to monitor their progress and hope for the best!

New Technique to Improve Crossflow Filtration

One of the biggest issues for crossflow filtration is figuring out how to control the loss of permeate flux in the process. Whether using reverse osmosis (RO), ultrafiltration (UF), or microfiltration (MF), the loss due to polarization and membrane fouling prevents many potential users in the biological or chemical processing fields from adopting this method.

If you are using crossflow filtration, or considering using it, and fear the effects of permeate loss, then you may want to consider this technique courtesy of North Carolina A&T University and the U.S. National Energy Technology Laboratory. Their study (see here) produced drastically improved results by implementing flow reversal to enhance the membrane flux.

They found that by periodically reversing the flow direction of the feed stream at the membrane surface results in prevention and mitigation of membrane fouling. This particular study conducted experiments with bovine serum albumin, Detran T-70, and apple juice. We’d love to hear from any of you in the field that may have tried this technique to see how it worked out!